Exposure can irritate the mouth, nose and throat. Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. Product form : Substance 77, No. ... Before use, please confirm the detailed method of use, precautions, and other information by using the technical documentation and Material Safety Data Sheet. (2) They shall come into force on the date of their publication in the Official Gazette. stream 3 0 obj IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Calcium Carbide can affect you when inhaled. acc. endobj Reaction with alcohols may form and explosive fulminate. When handling calcium chloride in the workplace, protect yourself from potential hazards by using safety glasses, a synthetic apron and gloves. P270Do not eat, drink or smoke when using this product. 3 Effective date : 01.31.2015 Page 1 of 7 Silver Nitrate,1.0N Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Make sure there are no flames in the area. Eng., 1966, 10, 334]. x��]�s�6�W��>��"��"H���ٲ�x��y#g���ZCIs�83'��~�A�$�r$ݦV�fݍ�F�� ��x�kV7�u���//��������Wۦ����������cu��T�j���_�W�/�,��'o�Dr�?=ɒ��' I�����MN8^��H�OO���\��\���vz�I*(IM3V&2O)Bӂ'������lz:E�U����|O��E����$�CԂ',O9|~��-���Z�ϋ7?�}�����y��7g�J>���� ���S���b[P+Kd$�FRF�DCX*r�"= 5Ms�M��.�����E�X`��Meɣ"�^y�YŰ,�O�����p�$�Y��>����H�wf��k@��b$La��a�Є�-.�e�a���$o>\&��G�8.߽N�����6��w��ՙN1(�S�La�,m��;b�ZK�Ҳ�j�Ls�1�`�ъ��%KI>�=���f�g����L~ 03����t?�a6h0�K����Y��g�l���M�9�c"�R�0�狷g|��U |��PaK��3��+�p��!�-��5�"���W��9_ܠ�usv. endobj Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. 4. The powdered mixture of the acetylide and iron oxide and iron chloride burns violently upon ignition, producing molten iron. - In these rules, unless the context otherwise requires,-(a) "Act" means the Petroleum Act, 1934 (30 of 1934); (b) "Carbide" means Calcium Carbide; endobj Warn observers that this is a loud explosion Perform this demonstration in a well-ventilated area only. 1 0 obj - (1) These rules may be called the Calcium Carbide Rules, 1987. MAKE SURE THAT THE PUMPKIN IS AT LEAST 10 FEET AWAY FROM STUDENTS WHEN PERFORMING DEMO. Calcium Carbide. Avoid formation of dust and aerosols.Further processing of solid materials may result in the formation of combustible dusts. <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/Annots[ 11 0 R] /MediaBox[ 0 0 595.32 842.04] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> 'w���mu6_.���_�՛���i�|�?U����u>�/��W��Y�����Vu.Y�ѱ�}�%��_�T�Kf"w���-�fx�h�nV�g�?ڭ���n��n!N=�(�\�4��p6��1V�Aѯz�>���iƊ�S��l�����+gX�z��;X�a�G\������{��)���@{���� Z"��ܐ �)@m��9#y !z*"HJsK "����HE���;������ �@Q 7P���e ���J�}|��u/{÷eGW�׽9�[�ۯ��S��#3An7��);��^X����~�^c�9��8*�:`K�$7�w�. Copper salt solutions would behave similarly, [Photogr. Immediately call a POISON CENTER or physician. CALCIUM CARBIDE is a reducing agent. P273Avoid release to the environment. 4/��.2~��uik��^$4#E �-Rf�9�(*��`{�3�pJV��r�ajDP�d:��1���8�( �\Aq�G�:6z3��T�[0��;��T�d��yqS� Very high temperatures, on the order of 3630 degrees Fahrenheit (2000 degrees C) are necessary to … Safety 1. $7.00 $ 7. 6.1.2. <> 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/10/2014 Revision date: 12/29/2016 Supersedes: 07/08/2016 Version: 1.2 Page 1 of 6 MSDS - Calcium Carbonate Material Safety Data Sheet (MSDS) - Calcium carbonate 1. Calcium Carbide Section 2. Hazards identification Response :IF exposed or if you feel unwell: Call a POISON CENTER or physician. Ultra high purity, high purity, submicron and nanopowder forms may be considered. Mixing calcium carbide with silver nitrate solutions forms silver acetylide, a highly sensitive explosive. Reaction with charcoal and shock may result in ignition. 2 0 obj 2. Safety Data Sheet acc. <> IF SWALLOWED: Immediately call a POISON CENTER or physician. Definitions. 2. 5. MATERIAL SAFETY DATA SHEET CALCIUM CARBIDE Carbide Industries Limited Althorpe Wharf Keadby Scunthorpe North Lincolnshire DN17 3DA Product name: CALCIUM CARBIDE CAS number: 75-20-7 EINECS number: 200-848-3 Index number: 006-004-00-9 Ingredient: CALCIUM CARBIDE TYPICAL CHEMICAL ANALYSIS Firefighters should wear self- contained breathing apparatus when fighting fires. Calcium carbonate is taken by mouth as an antacid for "heartburn." Calcium Oxide, (1305-78-8), 10-30%. $5.49 shipping. Thus, calcium carbide is a stable and inexpensive acetylene precursor that is available on the ton scale and it can be handled with standard laboratory equipment. P202Do not handle until all safety precautions have been read and understood. Section 4: First Aid Measures Always seek professional medical attention after first aid measures are provided. <>>> However, this is illegal in some countries as, in the production of acetylene from calcium carbide, contamination often leads to trace production of phosphine and arsine. <>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/Annots[ 13 0 R] /MediaBox[ 0 0 595.02 841.98] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Make sure that your hand is on the lid of the pumpkin so it is not ejected. stream - Packaging compatibilities Only packagings which are approved (e.g. <> 4.2 Specific precautions Calcium carbide is an irritant to the eyes, skin and respiratory system and can cause serious eye damages. classification, calcium carbide is listed as ‘Dangerous when Wet” and carries the UN1402 designation. <> Carbide lamps are still sometimes used in cave exploration. Rinse mouth. Amazingly, recent studies have revealed that calcium carbide, CaC 2, can be used as an easy‐to‐handle and efficient source of acetylene for in situ chemical transformations. Calcium Carbide is generally immediately available in most volumes. The work environment at the facility therefore requires stringent occupational controls to ensure safety on the plants. 3 0 obj Safety Precautions Calcium carbide is corrosive to eyes and skin and generates flammable acetylene gas when exposed to water or moisture. Calcium Chloride Safety, Handling & First Aid. Amazon's Choice for calcium carbide. Most metals form carbide compounds, though not all: Indium and Gallium, for example, do not. 1.1. Calcium Carbide can irritate the skin causing a rash, redness and burning feeling on contact. 77, No. Higher Carry out this demonstration on the scale provided and in a well-ventilated lab. %���� 3. S A Calcium Carbide (SACC), the local manufacturer of calcium carbide, carbide-based desulphuriser mixtures, acetylene and acetylene carbon black, has tightened safety … <>>> �� +��r��z���Zm.��fY+��W�Ң��/W�Ǩ�|�W�7N�h��v�����Dr��UQ#e�,HJƋx8V@YL�c�u܎1�Ja �D�F}�m��J���XI�3��p�@�n$!9��#t$��. Reactivity Profile. Product Information Outline. 00. Reaction with phosphorus, or sulfur, and shock may be violently explosive. Take appropriate precautions when performing the demo. to Regulation (EC) No. Calcium carbide is sometimes used as source of acetylene gas, which is a ripening agent similar to ethylene. Like most pyrometalurgical processes the manufacture of calcium carbide has hazards such as high temperatures, high voltages and currents and furnace reaction gases. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. 99. Carbides are compounds in which the anion is one or more carbon atoms. to ADR) may be used. *Glossary of terms relating to chemica and radiation hazards and haza?dous chemicals, 2 0 obj HAZARDS ASSOCIATED WITH CALCIUM CARBIDE 4.1 Health -Hazards 4.1.1 Calcium carbide as such is practically inert when dry but in the presence of water reacts exothermally to form acetylene gas and calcium. 4 0 obj It is necessary to produce calcium carbide industrially, because it is not naturally occurring in large amounts. endobj Identification . Calcium Carbide, (75-20-7), 65-85%. $24.99 $ 24. Calcium carbide is classified as a hazardous material due to the generation of acetylene gas, and as a - 6 - result, strict safety precautions must be used in handling the product. Ensure eyewash stations and washing facilities are located in the immediate workspace wherever this chemical is prevalent. PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:The reaction of calcium carbide with moisture is exothermic and may generate sufficient heat to ignite the acetylene gas formed. Calcium carbonate and calcium acetate are also taken by mouth to reduce phosphate levels in people with kidney disease. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. May react vigorously with oxidizing materials. The mixture of calcium carbide and sodium peroxide is explosive, as is calcium carbide and perchloryl fluoride as gases at 100-300\u00b0C. These materials are available from the relevant Division. Sci. 1 0 obj 4 0 obj Personal precautions, protective equipment and emergency procedures 6.1.1. Inhaling Calcium Carbide can irritate the lungs. Wear safety goggles. The potential for combustible dust formation should be taken into consideration before additional processing occurs. Safety Precautions Calcium carbide is corrosive to eyes and skin. endobj Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Calcium Carbide Lumps 50g Bottle. HQ Company Calcium Carbide Miners Grade. 4.8 out of 5 stars 182. %���� ��?�������S�Tԏ&0 �V�%#:��(�S�Y^�@�L$��F5���w�0CU�mB��SyA�,�.� c��Z��R$��]R�כ���24��`��ή�z�w�m=A�Uh����pY�N����y]����uHE�9�*����N2�y����M�Y.&�\8f ���ˮ�8f ����0��KXF�O�y-[*D�1,���?��YK Please request them. IntelliPERMIT has replaced a manual permit system at SACC. Calcium Carbonate Safety Data Sheet according to Federal Register / Vol. Calcium carbide must be kept dry since exposure to water or moisture generates flammable acetylene gas. x��Y[s7~g�����6hu�t2���]:��2}p�@L'/��k�V��ܾ�#m�],�'wK��e�]. Chemical Product and Company Identification Product Name : Calcium carbonate Catalog Codes : SLC1141, SLC4720, SLC4438, SLC1645 CAS# : 471 -34 -1 RTECS : FF9335000 TSCA : TSCA 8(b) inventory: Calcium carbonate Gloves must be inspected prior to use. Highly sensitive explosive is formed when calcium carbide is added to silver nitrate solution. Wash and dry hands. Acetylene gas is formed rapidly when calcium carbide is combines with water. 3 Effective date : 02.11.2015 Page 4 of 7 Calcium Carbide Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Store in a cool location.Keep away from food and beverages.Protect from freezing and physical damage.Provide ventilation for containers. 1907/2006 (REACH) Calcium carbide Revision: 2018 -09 07 Control of effects Protect against external exposure, such as Humidity - Ventilation requirements Use local and general ventilation. Calcium Chloride, Dihydrate Safety Data Sheet according to Federal Register / Vol. Per D.O.T. %PDF-1.5 P264Wash arms, hands and face thoroughly after handling. endobj HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid contact with skin and eyes. �DK�G$�Rjw���-�2������>N��.D�դ�j�+3k� *#-*�ˆ{�?.1�}z��?bB+�x��7P�T�ow$� ��M��a6��=~v��o��"�/���a�f�j�L�#5���l��S`����a For emergency responders ... MSDS CALCIUM CARBIDE - Material Safety Data Sheet CAS 75-20-7 Contact with acid or acid fumes can evolve heat and flammable vapors. 4.6 out of 5 stars 140. Avoid contact of chemicals with eyes and skin and follow all laboratory safety guidelines. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 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